Suppressing the Jahn–Teller effect in Mn-based Prussian blue analogues by linear (N[dbnd]O) anions

Abstract

Manganese-based Prussian blue analogues (PBAs) have been touted as a promising cathode material for sodium-ion batteries (SIBs) due to their low cost, long cycle life and high energy density. However, manganese-based PBAs perform poorly during cycling due to the Jahn-Teller effect. In this study, highly stable manganese nitrosylpentacyanoferrate (Mn[Fe(CN)5NO]) particles were synthesized using a simple hydrothermal method. The presence of nitroso group breaks the symmetry of the crystals to some extent, which is favorable to reduce the Jahn-Teller effect. Through experiments and DFT calculations, we confirm that the presence of linear (NO) anions reduces the lattice volume fluctuations of the samples during charging and discharging, thus contributing to the mitigation of the Jahn-Teller effect. The electrochemical properties of Mn[Fe(CN)5NO] were significantly improved compared to manganese hexacyanoferrate (MnFe[CN]6). Mn[Fe(CN)5NO] exhibited excellent sodium storage performance with an initial discharge capacity as high as 144.5 mAh/g at 20 mA g-1and capacity retention as high as 82.1 % after 400 cycles at 100 mA g−1. This Mn[Fe(CN)5NO] sample provides a promising cathode for sodium-ion batteries in large-scale energy storage systems.