Supported TiO2-ZnWO4 Photocatalytic Nanofibrous Membranes for Flow-Through and Fixed-Bed Reactors.

Abstract

We developed utilization models of supported electrospun TiO2-ZnWO4 photocatalytic nanofibrous membranes for air and water purifications using a noncomplex system with facile adaptation for large-scale processes. For this uniquely designed and multimode catalyst, ZnWO4 is selected for a visible light activity, while TiO2 is incorporated to enhance physical stability. Morphological structures of the TiO2-ZnWO4 membrane are characterized by scanning electron microscopy and scanning electron microscopy-energy-dispersive X-ray spectroscopy. The distinguished growth of ZnWO4 nanorods at the surface of the TiO2-ZnWO4 membrane is revealed by transmission electron microscopy (TEM). The relaxation process and charge transfer mechanism are proposed following the examination of interface and band gap (2.76 eV) between TiO2 and ZnWO4 particles via HR-TEM and UV-vis spectrophotometry. For the gas-phase reaction, a transparent photocatalytic converter is designed to support the pleated TiO2-ZnWO4 membrane for toluene decomposition under visible light. To obtain a crack-free and homogeneous fiber structure of the pleated TiO2-ZnWO4 membrane, 1 h of nanofibrous membrane fabrication via a Nanospider machine is required. On the other hand, a fiberglass-supported TiO2-ZnWO4 membrane is fabricated as a fixed-bed photocatalyst membrane for methylene blue decomposition under natural sunlight. It is observed that using the calcination temperature at 800 °C results in the formation of metal complexes between fiber glass and the TiO2-ZnWO4 membrane. The TiO2-ZnWO4 membrane successfully decomposes toluene vapor up to 40% under a continuous-flow circumstance in a borosilicate photocatalytic converter and 70% for methylene blue in solution within 3 h. Finally, the mechanically robust and supported TiO2-ZnWO4 nanofibrous membranes are proven for an alternate potential in environmental remediation.