Abstract
The supported CuO onto the ball-mill prepared clinoptilolite nanoparticles (CNPs) was prepared via an ion exchange process in Cu(II) aqueous solution followed by the calcination process. The CuO-CNP samples with various CuO loading were briefly characterized by XRD, FTIR, and DRS. pHpzc was varied in the range of 6.3 to 6.8 depending on the amount of loaded CuO in the samples. The band gap energy was estimated by applying the Kubelka-Munk equation on the DRS results that varied from 2.41 to 2.50 eV depending on the CuO loading. Based on the Scherrer equation nano-sized CuO-CNP at about 50 nm was estimated. The CuO-CNP contained 3.9% CuO showed the highest photocatalytic activity toward dichloroaniline (DCA). The effects of the experimental variables on DCA photodegradation were studied by using the Hinshelwood model. The optimal conditions for obtaining a higher rate for DCA photodegradation were the catalyst dose of 0.5 g/L, CDCA: 5 ppm, and the initial pH: 3. HPLC analysis of the photodegraded DCA solutions for 180 and 300 min gave the degradation extents 71% and 90%, respectively.
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