Abstract

The main focus of this study is exploring the spatial distribution of polyaromatics hydrocarbon links between oil spills in the environment via Support Vector Machines based on Kernel-Radial Basis Function (RBF) approach for high precision classification of oil spill type from its sample fingerprinting in Peninsular Malaysia. The results show the highest concentrations of Σ Alkylated PAHs and Σ EPA PAHs in ΣTAH concentration in diesel from the oil samples PP3_liquid and GP6_Jetty achieving 100% classification output, corresponding to coherent decision boundary and projective subspace estimation. The high dimensional nature of this approach has led to the existence of a perfect separability of the oil type classification from four clustered oil type components; i.e diesel, bunker C, Mixture Oil (MO), lube oil and Waste Oil (WO) with the slack variables of ξ ≠ 0. Of the four clusters, only the SVs of two are correctly predicted, namely diesel and MO. The kernel-RBF approach provides efficient and reliable oil sample classification, enabling the oil classification to be optimally performed within a relatively short period of execution and a faster dataset classification where the slack variables ξ are non-zero.

Highlights

  • Millions of marine species that are inhabiting the oceans can be endangered if fuel oil is released into the sea or ocean (Gaganis & Pasadakis )

  • This paper presents Support vector machines (SVM) based on the Kernel – Radial Basis Function (RBF) algorithm, which was applied as a development approach for oil spill type classification using gas chromatography- flame ionization detector (GC-flame ionization detector (FID)) and gas chromatography-mass spectrometry (GC-MS)

  • We have explored a wide range of applications considering the RBF-SVM model as a decision function classifier to gain high precision of oil type classification performance from the oil spill fingerprints

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Summary

INTRODUCTION

Millions of marine species that are inhabiting the oceans can be endangered if fuel oil is released into the sea or ocean (Gaganis & Pasadakis ). The high complexity of the data requires an in-depth study on the restructuring of the data classification into the desired categories that is in line with the global scale in terms of competitiveness (Alamdar et al ) Using innovative methods such as the gas chromatography- flame ionization detector (GC-FID) and gas chromatography-mass spectrometry (GC-MS) enables the oil spill fingerprinting to be used as source identification, oil spill characterization and an environmental forensics technique. The building of substantial non-linear classification boundaries was performed by the kernel function of SVM, as an alternative measure in pattern recognition (Dufrenois & Noyer ) This learning machine enables the improvement of the output results of GC-FID and GC-MS to achieve the best oil type classification and higher profit with no unstable patterns (overfitting).

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