Support effects and catalytic trends for water gas shift activity of transition metals

Abstract

Water gas shift activity measurements for 12 transition metals (Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Re, Ir, Pt, Au) supported on inert MgAl 2O 4 and Ce 0.75Zr 0.25O 2 are presented, to elucidate the influence of the active metal and the support. The activity is related to the adsorption energy of molecular CO and atomic oxygen on the metal; the latter is a good measure for the reactivity of the metal towards H 2O. Generally, the activity of the catalysts with the Ce 0.75Zr 0.25O 2 support is higher, compared to the corresponding MgAl 2O 4-supported catalysts. Exceptions are Cu and Au, which have a higher activity on the MgAl 2O 4 support and are both characterized by weak CO adsorption. For the MgAl 2O 4-supported catalysts a volcano-type relation between the activity and the adsorption energy of atomic oxygen on the metal is obtained. The maximum activity is found for metals with a binding energy of oxygen around −2.5 eV. No clear correlation exists with the adsorption energy of CO. In contrast, the activity for the Ce 0.75Zr 0.25O 2 support increases with increasing adsorption strength for CO, and based on a relatively low activity of Cu the activity does not seem to depend on the adsorption energy of oxygen. Such a change in activity-descriptor for the different supports can be rationalized by the possibility that water dissociation occurs on the redox-active Ce 0.75Zr 0.25O 2 support, whereas the MgAl 2O 4 support is inactive.