Abstract
Reported here are three new In–Se open frameworks with unique polyselenide ion as linker. Single-crystal X-ray diffraction analyses demonstrate that supertetrahedral Tn (n = 2, 3) clusters serving as secondary building units in these compounds are connected via polyselenide ligands to form the interrupted or elongated diamond topologies. UV–vis absorption analysis and photoelectric response measurements indicate that these In–Se frameworks retain semiconductor properties, making them potential candidates in photocatalytic applications.
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