Abstract

Nonradiative recombination (NRR) centers in n-AlGaN layers of UV-B AlGaN samples with different numbers of superlattice (SL) periods (SLPs), grown on the c-plane sapphire substrate at 1150 °C by the metalorganic chemical vapor deposition technique, have been studied by using below-gap-excitation (BGE) light in photoluminescence (PL) spectroscopy at 30 K. The SLP affects the lattice relaxation of the SL and n-AlGaN layer. The PL intensity decreased by the superposition of BGE light of energies from 0.93 eV to 1.46 eV over the above-gap-excitation light of energy 4.66 eV, which has been explained by a two-level model based on the Shockley–Read–Hall statistics. The degree of PL quenching from n-AlGaN layers of the sample with SLP 100 is lower than those of other samples with SLP 50, 150, and 200. By a qualitative simulation with the dominant BGE energy of 1.27 eV, the density ratio of NRR centers in n-AlGaN layers of 50:100:150:200 SLP samples is obtained as 1.7:1.0:6.5:3.4. This result implies that the number of SLP changes lattice relaxation and determines the density of NRR centers in the n-AlGaN layer, which affects the performance of LEDs.

Highlights

  • The demand of cheap, environmentally friendly, and smart AlGaN ultraviolet (UV) light emitters in the UV-B spectral range between 280 nm and 320 nm has arisen because of their legionary potential applications.[1,2,3,4,5,6,7,8] The conventional light sources in the aforesaid spectral ranges are bulky, have limited lifetime, and contain toxic substances.[9]

  • This result implies that the number of superlattice periods (SLPs) changes lattice relaxation and determines the density of Nonradiative recombination (NRR) centers in the n-AlGaN layer, which affects the performance of LEDs

  • In order to corroborate our qualitative interpretations, for the results shown in Figs. 6, 7, and 9 by the two-level model, a semiquantitative simulation of the two-wavelength excited PL (TWEPL) results was carried out for the most dominant PL quenching occurred by the 1.27 eV BGE energy

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Summary

Introduction

The demand of cheap, environmentally friendly, and smart AlGaN ultraviolet (UV) light emitters in the UV-B spectral range between 280 nm and 320 nm has arisen because of their legionary potential applications.[1,2,3,4,5,6,7,8] The conventional light sources in the aforesaid spectral ranges are bulky, have limited lifetime, and contain toxic substances.[9] UV-B LEDs are promising devices, but their reliability still needs improvement.[10] One of the main reasons for the low efficiency of UV-B LEDs is the non-radiative recombination (NRR) losses [Shockley–Read–Hall (SRH) and Auger-related].9. One of the main reasons for the low efficiency of UV-B LEDs is the non-radiative recombination (NRR) losses [Shockley–Read–Hall (SRH) and Auger-related].9 Recent studies have indicated that the reduction in optical power with an increase in the temperature (thermal droop) may limit the performance of GaN-based

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