Superior filaments-based fabric with thermal-mechanical-electrical coupling properties for remote temperature alarm

Abstract

The safeguarding fabrics featuring good thermal insulation, flame retardancy, and force dissipation simultaneously remain challenging due to the current filaments with limited properties. Herein, a novel and flame-retardant filament (F-filament) is developed by hot-extruding the mixture of shear stiffening gel/thermoplastic polyurethane (SSG/TPU) and microencapsulated ammonium polyphosphate (MHAPP), which is conducive to knitting protective fabrics. The conductive F-filament (cF-filament) is further prepared by incorporating with MXene. The F-filament-based fabrics present better anti-impact properties than commercial fabrics and can dissipate 6.32 kN impacting force to 1.89 kN. The patterned knitted fabric also facilitates heat exchange, reducing the contact temperature of the body surface to approximately 37 °C when exposed to an 80 °C heat source, effectively avoiding thermal damage through its porous structure. Moreover, the F-filament-based fabrics are intact even after 19 s of continuous burning. Notably, the cF-filament is demonstrated for use as a sensor for real-time multimodal monitoring, such as detecting external mechanical loadings and temperature stimuli. The cF-filament sensor can be integrated into the F-filament-based knitted fabrics, which accurately realizes environmental monitoring and explores the best-escaping route through a remote temperature alarm system.