Abstract
Lead-free dielectric ceramics, as the crucial materials for the development of eco-friendly high pulse power devices, have faced limitations in achieving energy storage performance comparable to lead-based counterparts. A novel strategy was adopted to enhance the energy storage capability of Bi0.5Na0.5TiO3 based ceramics by constructing multiple phase structures and multi-size domain. An ultrahigh energy storage density of 8.0 J·cm−3 and a large efficiency of 88.9 % were achieved. The superior energy storage properties can be attributed to the synergistic effects of multiple phase structures and multi-size domain construction resulted from a significant polarization intensity difference upon Sr(Zr0.2Ti0.8)O3 doping. Even more surprising, the 0.6Bi0.5Na0.5TiO3-0.4Sr(Zr0.2Ti0.8)O3 ceramic exhibited excellent aging resistance, with variation in discharge energy density (Wd) < ±7% over a temperature range from 20 to 150°C, variations in recoverable energy density (Wrec) < ±8.3 %, and efficiency (η) < ±5.6 % over a frequency range from 1 to 50 Hz and across 105 cycles. The finding in this work not only provides an effective candidate for high power pulse capacitors, but also provides ideas for the study of high energy storage performance of BNT and the related lead-free ceramics.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
