Superhydrophobic starch-based adsorbent with honeycomb coral-like surface fabricated via facile immersion process for removing oil from water

Abstract

The development of novel superhydrophobic adsorbents is highly demanded for tackling frequent oil spill accidents. Porous starch-based materials have been proven to possess good oil absorption performance, but their superhydrophobicity has not yet been reported, thus limiting their application in oil spill cleanup. Herein, a superhydrophobic starch-based adsorbent (MSC) was fabricated through the facile immersion process of starch cryogel (SC) into toluene solution of methyltrichlorosilane (MTS). Low-surface-energy and honeycomb coral-like micro/nanostructures, which contribute to high water contact angle (>151.0°) and low sliding angle (<15.0°), were provided simultaneously to SC by the hydrolysis-condensation reaction of MTS. MSC exhibited excellent water repellent, self-cleaning, and anti-fouling properties, as well as passable mechanical and chemical durability. The reasonable oil adsorption performance and selective wettability toward oil and water allowed this absorbent to be applied for heavy oil removal underwater and oil slick cleaning from the water surface. It is expected that the facile strategy provided by this work will accelerate the application of superhydrophobic starch-based materials in oil contamination removal and other industrial activities.