Superhydrophobic Foams with Chemical- and Mechanical-Damage-Healing Abilities Enabled by Self-Healing Polymers.

Abstract

The fabrication of superhydrophobic materials capable of spontaneously healing both chemical and mechanical damages at ambient conditions has been a great challenge but highly desired. In this study, we propose that a self-healing hydrophobic polymer can be used to induce self-healing in a superhydrophobic material. As a demonstration, stable and porous self-healing superhydrophobic foams are fabricated by casting a mixture of healable poly(dimethylsiloxane) (PDMS)-based polyurea, multiwalled carbon nanotubes (MCNTs), and table salt, followed by solvent evaporation and removal of the salt template. The PDMS-based polyurea is able to heal mechanical damage by reforming hydrogen bonds and can also reverse chemical damage through surface reorganization. Thus, the chemically and mechanically damaged foams can spontaneously restore their superhydrophobicity and structural integrity at ambient conditions. Moreover, because of the satisfactory photothermal conversion of MCNTs, the temperature of the self-healing superhydrophobic foams can rapidly reach 60 °C under sunlight, which greatly increases the healing speed and healing efficiency of the foam.