Abstract

A supercooled disk electrode is fabricated, around which the temperature of aqueous solution is below its normal freezing point. The supercooled electrode demonstrates thermal stability and its surface temperature can be adjusted by changing an additional heating current. Theoretical simulation shows that the supercooled region is restricted within a small volume around the disk electrode. The electrochemical behavior of cytochrome c was investigated at supercooled electrode for the first time.

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