Abstract

A ternary silicide Ca(Al0.5,Si0.5)2 was prepared by Ar arc melting. Powder x-ray diffraction measurement indicates that it has the AlB2-type structure with lattice constants of a=4.1905(5) and c=4.3992(8) Å, where Si and Al atoms are arranged in the disordered honeycomb lattice and Ca atoms are intercalated between them. The silicide is isostructural with a superconductor MgB2. Electrical resistivity and dc magnetization measurements revealed that it is a superconductor with a TC of 7.7 K.

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