Superconductivity in non-centrosymmetric ZrNiAl and HfRhSn-type compounds

Abstract

We report the discovery of superconductivity in non-centrosymmetric compounds HfNiAl, ZrNiAl, ZrNiGa, and HfPtAl by measuring their electrical transport and thermodynamic properties. HfNiAl, ZrNiAl, and ZrNiGa crystallize in the ZrNiAl-type crystal structure, whereas HfPtAl crystallizes in the HfRhSn-type crystal structure. Superconducting transitions for HfNiAl, ZrNiAl, ZrNiGa, and HfPtAl are observed at 1.0 K, 1.0 K, 0.42 K, and 0.58 K, respectively. Using the Werthamer–Helfand–Hohenberg model, the zero-temperature upper critical fields µ 0H(0) were estimated to be 0.58 T, 0.24 T, 0.08 T, and 0.34 T for HfNiAl, ZrNiAl, ZrNiGa, and HfPtAl, respectively. The observed jump in electronic heat capacity () across the superconducting transition is 1.3, 1.3, and 1.2 for HfNiAl, ZrNiAl, and HfPtAl, respectively. After the inclusion of the spin–orbit coupling in the band structure calculations, a total of six bands for ZrNiAl, HfPtAl, and ZrNiGa, and eight bands for HfNiAl were found to cross the Fermi level. Spin–orbit coupling induced maximum splitting (/k B T c) of the electronic bands near the Fermi level was found to be 1697, 517, 1138, and 4230 for HfNiAl, ZrNiAl, ZrNiGa, and HfPtAl, respectively. Large variation of the antisymmetric spin–orbit coupling (ASOC) among these compounds provides a great opportunity to study the effects of ASOC on the superconducting pairing states.