Superconductivity and physical properties of CaPd2Ge2 single crystals

Abstract

We present the superconducting and normal state properties of CaPd2Ge2 single crystals investigated by magnetic susceptibility χ, isothermal magnetization M, heat capacity Cp, in-plane electrical resistivity ρ and London penetration depth λ versus temperature T and magnetic field H measurements. Bulk superconductivity is inferred from the ρ(T) and Cp(T) data. The ρ(T) data exhibit metallic behavior and a superconducting transition with Tc onset = 1.98 K and zero resistivity at Tc 0 = 1.67 K. The χ(T) reveals the onset of superconductivity at 2.0 K. For T > 2.0 K, the χ(T) and M(H) are weakly anisotropic paramagnetic with χab > χc. The Cp(T) data confirm the bulk superconductivity below Tc = 1.69(3) K. The superconducting state electronic heat capacity is analyzed within the framework of a single-band α-model of BCS superconductivity and various normal and superconducting state parameters are estimated. Within the α-model, the Cp(T) data and the ab plane λ(T) data consistently indicate a moderately anisotropic s-wave gap with Δ(0)/kBTc ≈ 1.6, somewhat smaller than the BCS value of 1.764. The relationship of the heat capacity jump at Tc and the penetration depth measurement to the anisotropy in the s-wave gap is discussed.