Abstract

Solid solution of Gd(Ba2-xGdx)Cu3Oy was synthesized by a citrate pyrolysis process, and characterized by X-ray powder diffraction, iodometric titration, electrical resistivity and magnetization. The solubility limit have been found to extend up to x=0.4. The orthorhombic distortion decreases with increasing x and the compound becomes tetragonal for x>0.2. Superconductivity can be observed in the orthorhombic phase as well as in the tetragonal phase but only for samples with a metal-like resistivity (x<0.3). The antiferromagnetic ordering temperature TN is 2.24 K for sample with x=0 and increases to 2.45 K for x=0.2.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.