Abstract

We report ${}^{15}\mathrm{N}$ nuclear magnetic resonance (NMR) and the nitrogen-isotope effect studies on c-axis oriented sample of Li-doped HfNCl with superconducting transition temperature ${T}_{c}\ensuremath{\sim}25.5\mathrm{K}.$ ${}^{15}\mathrm{N}$ NMR Knight shift decreases toward zero below ${T}_{c},$ giving evidence that the pairing symmetry is an even-parity spin singlet, and that the nitrogen site plays an important role in the occurrence of superconductivity. A nitrogen isotope shift is found to be quite small, $\ensuremath{\Delta}{T}_{c}\ensuremath{\sim}0.1\mathrm{K}$ $({\ensuremath{\alpha}}_{N}=0.07\ifmmode\pm\else\textpm\fi{}0.02),$ which cannot reproduce such a high ${T}_{c}$ within the traditional BCS framework.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.