Super-Exchange Interaction in a Chair-Piperazine Bridged Dicopper(II/II) Complex: Synthesis, Crystal Structure, Magnetic Properties and Molecular Orbital Calculations

Abstract

Abstract Reaction of the /i-bis(tridentate) ligand H3L' (L' = 1,3-bis[N-(5-cliloro-2-hydroxybenzylidene)- 2-ainiiioetliylene]-2-(5-cliloro-2-hydroxy!phenyl)iniidazoliduie) with eopper(II) chlonde diliydrate gives the chair-piperazine bridged complex [Cu2(μ-L)Cl2]. The halves of the binuclear complex are related by crystallographic inversion symmetry. The intramolecular Cu ・・・Cu separation is 6.954(3) Å. Temperature-dependent magnetic susceptibility measurements of the complex show a weak intramolecular antiferromagnetic eouphng. The super-exchange coupling constant (J) is - 10.5 cm-1. Semi-empirical extended Huckel molecular orbital (EHMO) calculations have been performed in order to gain msight into the molecular orbitals that participate in the super-exchange pathway.