Sunn hemp hessian cloth reinforced thermoplastic composites: Effects of chemical treatment and gamma-ray irradiation

Abstract

Untreated and alkali-treated Sunn hemp hessian cloth-reinforced high-density polyethylene (HDPE) composites were prepared by the compression molding method. The fabricated composites contained 40, 45, 50, 55, 60, and 65wt% fiber contents and were optimized. 55wt% fiber contents reinforced composites showed better mechanical properties. This composite was alkali treated and irradiated under gamma-ray at doses 2.5‒7.5 kGy at the rate of 6 kGy/h. The X-ray diffraction (XRD) result indicates that the crystallinity of the alkali-treated Sunn hemp-reinforced HDPE composites shows a higher value than those of untreated and irradiated composites. Better adhesion between fiber and matrix was observed from surface micrographs. Fourier-transform infrared (FTIR) spectroscopy reveals cross-linking between fiber and matrix. The water intake properties of irradiated composite show more hydrophobic nature than that of untreated and alkali-treated composites. The tensile strength of the gamma-ray irradiated composites are 20% and 33% greater than that of untreated and alkali-treated composites. Similar results are found for Young’s modulus. At a certain dose of 5 kGy, the irradiated composites show improved thermal, mechanical, and structural properties than untreated and alkali-treated composites.