Sunlight-induced enhanced photocatalytic reduction of chromium (VI) and photocatalytic degradation of methylene blue dye and ciprofloxacin antibiotic by Sn3O4/SnS2 nanocomposite

Abstract

Detection of residual organic and inorganic species in water bodies, including drinking water, has led to developing strategies for their removal. Here, we report a very efficient method of removing Cr(VI), organic dye, and antibiotic from water using atype-II heterojunction based onSn3O4/SnS2 solar photocatalyst. The toxic Cr(VI) species are reduced by photocatalytic methodology, while methylene blue (MB) dye and ciprofloxacin (CIP) antibiotics are removed by photocatalytic degradation. The structural, compositional, morphological, and optical properties of the hydrothermally synthesized photocatalyst have been studied. Under sunlight exposure, more than 99.9% of Cr(VI) is reduced within 60min at a reaction rate of 0.066min-1. While 99.6% of MB and 90% of CIP degradation are achieved in 90min and 120min, corresponding to photocatalytic degradation rates of 0.043min-1 and 0.019min-1, respectively. The total organic carbon after degradation corresponded to 85.1% for MB and 72.4% for CIP mineralization. The observedphotocatalytic degradation is attributed to in situ generation of reactive oxygen species (ROS), e.g., superoxide radicals and hydroxyl radicals. The role of ROS towards photocatalytic degradation of MB and CIP, respectively, was confirmed from ROS scavenging studies. The MB and CIP degradation mechanism has been discussed by analyzing their degradation products.