Abstract

Reactions between Ph 3SnCH 2SAr and 2-NO 2C 6H 4SCℓ lead to the formation of 2-(ArSCH 2-6-NO 2C 6H 3SSC 6H 4NO 2-2 via the [2,3]sigmatropic rearrangement of the S-arylthio-sulphonium ylides C H 2 S + (Ar)SC 6H 4NO 22.

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