Abstract
Abstract Cyclic thionylphosphazenes 1 undergo thermal ring-opening Polymerization (TROP) to yield poly(thionylphosphazenes) 2 with backbones of four coordinate sulfur(VI), nitrogen, and phosphorus atoms. During TROP of 1, macrocycles with analogous skeletal compositions were also formed. Isolation, characterization and thermolysis studies of these species are described.
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