Sulfur vacancies-induced electron delocalization effect of cobalt sulfide for enhanced catalytic activation of peracetic acid and norfloxacin degradation

Abstract

Antibiotics have attracted widespread attention due to their potential risks to human health and environment. In this study, a heterogeneous advanced oxidation process (AOP) of peracetic acid (PAA) activation by cobalt material was developed to degrade a typical antibiotic, norfloxacin (NOR). Cobalt sulfide materials with sulfur vacancies (CoSx) were synthesized through a two-step hydrothermal process. The optimized material (CoSx-2) could efficiently activate PAA system, achieving 91.8% NOR degradation in 5 min. The Co(II)/Co(III) species in CoSx was key to activating PAA, as Co(II) initiated the reaction and Co(III) activation caused the production of CH3C(=O)OO• species. Moreover, the presence of sulfur vacancies (VS) led to the generation of hydroxyl radicals (•OH) and singlet oxygen (1O2) via chain reactions with CH3C(=O)OO•. Density functional theory (DFT) calculations reveal the contribution of VS to enhanced catalytic PAA activation, as the lower work function (5.76 eV), higher adsorption energy (-3.43 eV), bridge effect of delocalized electrons and shifted d-band center are achieved to reduce the energy barrier for electron transfer during catalytic reaction. In addition, DFT calculation on Fukui index further explains that 18 N and 21 N are reactive sites of NOR for electrophilic attack, leading to primary degradation pathways of C–N cleavage, defluorination, dealkylation and hydroxylation. This study gives a new perspective on the regulation of material structure for efficient activation of PAA and promotes the practical application of heterogenous PAA-based AOPs for emerging contaminants removal in water treatment process.