Sulfur Poisoning of SOFC Anodes: Effect of Overpotential on Long-Term Degradation

A Hauch,T Ramos,J Hjelm,A Hagen

doi:10.1149/2.080406jes

Abstract

Sulfur impurities in carbon containing fuels for solid oxide fuel cells (SOFC), e.g. natural gas and biogas, typically lead to significant losses in performance due to the sulfur sensitivity of Ni/yttria-stabilized-zirconia (YSZ) anodes for SOFC. Full cells having Ni/YSZ anodes have been characterized during long-term galvanostatic operation in internal reforming gas mixture (CH4/H2O/H2:30/60/10), with 2 ppm H2S exposure to the anode for 500 hours at 850°C, at different current densities. This work focus on the long-term effect of H2S exposure over a few hundreds of hours; and describes and correlates the observed evolution of anode performance, over hundreds of hours, with sulfur exposure at low cell overpotential (low current density) and at high overpotential (high current density) with and without H2S exposure. For tests at low overpotential with H2S exposure only a reversible loss in performance was observed and post-mortem SEM analysis showed an intact Ni/YSZ anode microstructure. For tests at high cell overpotential the H2S exposure caused both a reversible loss in performance and an irreversible long-term degradation. Post-mortem SEM analysis of the Ni/YSZ anode from this tests showed increased porosity and lack of percolating Ni in the few microns of the anode closest to the anode/electrolyte interface.

Highlights

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Fewer results are reported on the long-term, and often irreversible, loss of performance due to sulfur poisoning,[5,8,10] even though this will inevitably be of high importance for solid oxide fuel cells (SOFC) as an emerging energy conversion technology
Based cells can be forced into a regime where the initial and reversible degradation due to the addition of 2 ppm H2S is followed by an almost linearr and irreversible degradation of the anode

Summary

Introduction

General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. A tape cast Ni/ScYSZ based cell showed similar high degradation rates for the long-term degradation as the Sc-free YSZ-Hi-Spr and YSZ-Hi (in this work) upon H2S poisoning tested under similar conditions at high overpotential.11

Results

Conclusion