Abstract

Heteroatom-doped porous carbon materials are very attractive for lithium ion batteries (LIBs) owing to their high specific surface areas, open pore structures, and abundant active sites. However, heteroatom-doped porous carbon with very high surface area and large pore volume are highly desirable but still remain a big challenge. Herein, we reported a sulfur-doped mesoporous carbon (CMK-5-S) with nanotubes array structure, ultrahigh specific surface area (1390 m2/g), large pore volume (1.8 cm3/g), bimodal pore size distribution (2.9 and 4.6 nm), and high sulfur content (2.5 at%). The CMK-5-S used as an anode material for LIBs displays high specific capacity, excellent rate capability and highly cycling stability. The initial reversible specific capacity at 0.1 A/g is as high as 1580 mAh/g and simultaneously up to 701 mAh/g at 1 A/g even after 500 cycles. Further analysis reveals that the excellent electrochemical storage performances is attributed to its unique structures as well as the expanded lattice by sulfur-doping.

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