Abstract
Pyrite has a poor {001} cleavage. Unlike most other minerals with a rocksalt-type structure, pyrite typically fractures conchoidally, demonstrating that parting surfaces are not constrained to the {001} crystallographic plane. Cleavage along {001} require rupture of only Fe-S bonds, but pyrite consists of both Fe-S and S-S bonds. Analysis of bond energies indicates that S-S bonds are the weaker bonds and they are likely to be ruptured when pyrite is fractured. With each ruptured S-S bond, two mononuclear species (formally S 1- ) are produced, one bound to one fracture surface and the second to the opposite fracture surface. This monomer is reduced to S 2- (monosulfide) during relaxation through oxidation of surface Fe 2+ ions to Fe 3+ . These surface relaxation processes explain the surface states observed in S(2p) and Fe(2p 3/2 ) X-ray photoelectron spectra (XPS) of pyrite. The S(2p) XPS spectrum is interpreted to include bulk disulfide contributions at 162.6 eV and two surface state contributions at 162.0 and 161.3 eV. The monosulfide (S 2- ) emission is near 161.3 eV, as observed in S(2p) spectra of pyrrhotite, and the 162 eV peak is interpreted to result from the surface-most sulfur atom of surface disulfide ions. The Fe(2p 3/2 ) XPS spectrum includes three contributions, a bulk Fe 2+ emission near 707 eV and emissions from two Fe surface states. One surface state is interpreted to be Fe 2+ surface ions. Their coordination is changed from octahedral before fracture to square pyramidal after fracture. The consequent stabilization of the antibonding Fe d 2 z orbital yields unpaired electrons in the valence band resulting in multiplet peak structure in the Fe(2p 3/2 ) spectrum. Similarly, each surface Fe 3+ ion, having contributed a non-bonding 3d electron to the valence band (bonding orbital), contains unpaired 3d electrons, resulting in multiplet splitting of its Fe(2p 3/2 ) signal. The high-energy tail observed in the Fe(2p 3/2 ) spectrum of pyrite is the product of emissions from both surface states with Fe 2+ multiplet peaks centered near 708 eV and the surface Fe 3+ multiplets spanning the binding energies from 708.75 to about 712 eV.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
