Successful Application of a Differentiated Chelant-Based Hydrofluoric Acid for the Removal of Aluminosilicates, Fines, and Scale in Offshore Reservoirs of the Gulf of Mexico

Abstract

Abstract The Ewing Bank 873 (EW 873) Field is an offshore mature field in the Gulf of Mexico that produces hydrocarbon from Pliocene stacked turbidite sands. Wells in the EW 873 Field have experienced production impairment from formation damage, such as aluminosilicates, fines, and scale, including calcium carbonate (CaCO3) and barium sulfate (BaSO4). This paper discusses the results of the successful application of a differentiated chelant-based hydrofluoric (HF) acid to remove formation damage and enhance oil production (by as much as 305%) from Well A-04 in the EW 873 Field. Additionally, the paper presents the chemical analyses of the acid flowback as well as the methods used to characterize the formation damage. More importantly, the paper also focuses on the research efforts that led to the development and successful application of the differentiated chelant-based HF acid. Throughout the research, analytical experiments and corefloods were performed with different acid formulations on cores that contained acid-sensitive clays, CaCO3 and BaSO4. Two formulations contained alpha-hydroxycarboxylic (a-HCA) HF acids, and other formulations contained chelants and chelant HF acids, which were both based on an aminopolycarboxylic acid (APCA). The APCA/HF acid proved to be the most effective formulation, as it achieved the highest permeability increase (relative to brine) and dissolved ions while mitigating precipitation. Furthermore, the APCA/HF acid is biodegradable, and compatibility and corrosion testing indicated that it is compatible with the produced oil samples of Well A-04 and it exhibits low corrosion loss (< 0.05 lbm/ft2) when applied with a chosen corrosion inhibitor on 13-Cr metallurgy, respectively. The development of this differentiated APCA/HF acid highlights the potential of performing successful acid jobs where complex mineralogies, such as CaCO3 and BaSO4, are present.