Subsurface Submergence of Mine Waste Materials as a Remediation Strategy to Reduce Metal Mobility: an Overview

Abstract

The most common lead (Pb) and zinc (Zn) ore minerals are galena (PbS) and sphalerite (ZnS). Milling and mining operations of these ores produce huge amounts of waste known as chat and tailings. Chat is composed of gravel, sand, and silt-sized rock materials, whereas tailings are often fine-grained and silt-sized particles with higher toxic element concentrations. Upon oxidation, tailings with high pyritic materials release Pb, Zn, Cadmium (Cd), and other elements associated with ores affecting plant productivity, the ecosystem, and human health. This article is an overview on utilizing the subsurface submergence technique for mitigating environmental impacts from abandoned mine waste materials. In the past, researchers have studied the influence of submergence on these elements; however, an emphasis on gathering a detailed understanding of such redox-based remediation processes is not that common. We reviewed literature that evaluated water chemistry, solid phases, and association of trace elements, and addressed utilization of surface amendments of mine tailings for predicting their interactions within sediments and overlying waters. Case studies specifically focused on mining of Pb and Zn, including a recent study conducted in the Tri-State mining district (Kansas, Missouri, and Oklahoma), are presented to add a more comprehensive understanding of biogeochemical transformations of trace elements present in mine waste materials under a long-term submergence. The purpose of this article is to present evidence on the viability of subsurface disposal of mine waste materials, in order to design effective remediation and mitigation strategies to protect human and environmental health in the global dimension.