Abstract
The study of the regioselectivity of the addition of a nucleophile to chlorotoluenetricarbonylchromium complexes, under cine or tele S NAr conditions, indicated that stabilized carbanions added predominantly to the carbon eclipsed by a CrCO bond of the most stable conformer. The conformation of p-chlorotoluenetricarbonylchromium has been studied, in solution by 1H NMR and in the solid state by X-ray crystallography.
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