Abstract
Fe(cot) 2 (cot = cyclooctatetraene) reacts with certain phosphines and phosphites to give Fe(cot)L 3 compounds in good yield. Reaction of Fe(cot) 2 with Ph 2PCH 2CH 2PPh 2 under N 2 gives a complex containing coordinated dinitrogen, which is converted into Fe(cot)(Ph 2PCH 2CH 2PPh 2)(CO) on reaction with CO or formate esters.
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