Abstract
In the diphosphirane series, the substitution of one aryl group (2,4,6-tri-tert-butyl‐phenyl) by a chlorine atom leading to the trans P‐chloro-diphosphirane via the cis isomer intermediate can be readily realized in chlorinated solvent under sonication or in the presence of gaseous hydrogen chloride in diethyl ether at room temperature.
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