Abstract

Using the Wilson FG matrix method, potential constants were determined for the CH2F2 molecule using the most general quadratic potential function. The same constants were used to calculate the wave numbers of the fundamentals of the CHDF2 and CD2F2 molecules. Finally, the heat content, free energy, entropy, and heat capacity were calculated for all three molecules for 12 temperatures from 100° to 1000°K, for the ideal gaseous state at 1-atmos pressure.

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