Abstract
Raman displacements, semiquantitative relative intensities, and quantitative depolarization factors of liquid CBr2F2, and infrared wave numbers and the percent transmission in the region 450–4000 cm−1 for gaseous CBr2F2 have been obtained. Satisfactory assignments were made for all the observed bands. Using the Wilson FG matrix method, with a potential function containing all possible second-degree terms, reasonable values of the potential constants were calculated. Finally, the heat content, free energy, entropy, and heat capacity for the ideal gaseous state at 1 atmos pressure were calculated for 12 temperatures, from 100 to 1000°K, using a rigid rotator, harmonic oscillator approximation.
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