Abstract

Substituted metal carbonyls. Part 24. Heteropolymetallic oligomers [(OC)<sub>x</sub>M′(µ-L–L)M(CO)<sub>4</sub>(µ-L–L)M′(CO)<sub>x</sub>] and [(OC)<sub>5</sub>Mn–Mn(CO)<sub>4</sub>(µ-L–L)M(CO)<sub>4</sub>(µ-L–L)(OC)<sub>4</sub>Mn–Mn(CO)<sub>5</sub>][M = Cr, Mo or W; M′= Cr, Mo, W (x= 5) or Fe (x= 4); L–L = Fe(C<sub>5</sub>H<sub>4</sub>PPh<sub>2</sub>)<sub>2</sub>or Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>m</sub>PPh<sub>2</sub>(m= 2 or 3)], with metal carbonyl and diphosphine repeating units

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