Abstract
Diazeniumdiolates (RN(O)NO−, R=Et, Et2N) react in an R-dependent manner with Wilkinson's catalyst to give either a chelated square-planar complex, Rh(η2-O2N2Et)(PPh3)2, 1, for R=Et, or with initial chelation followed by reductive nitrosylation to give Rh(NO)(PPh3)3, in the case of R=Et2N. Methyl iodide oxidatively adds to 1 to give RhIMe(η2-O2N2Et)(PPh3)2, 2, as a pair of isomers a, major, and b, minor. Both 1 and 2a have been structurally characterized by single-crystal X-ray diffraction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
