Abstract
Subsolidus phase relations in the ternary system TiO2–BaO–B2O3 were analysed with X-ray diffraction. According to the constructed phase relations, 15 ternary phase regions were identified in the subsolid phase, in which 11 binary compounds and 2 ternary compounds were investigated in detail. Additionally, the crystallisation region of rutile was identified, and it was found that rutile crystal with dimension of 10×4×2 mm was grown through spontaneous nucleation from a new flux BaO–B2O3.
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