Abstract

Near-field fluorescent spectroscopy was used to characterize the grain boundary of Cr-doped polycrystalline alumina. The results show that the peak widths in near-field spectra are narrower than in spectra obtained by conventional microspectrometry, and this is attributed to the difference in spatial resolution of the two methods. The R-line peaks of Cr 3+ fluorescence were observed to shift to a lower wavelength at the grain boundary compared to the bulk crystal, which is attributed to stress relief at the crystal boundary. This peak shift at the boundary decreases as a function of the time a polycrystal is annealed at 1700 °C.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.