Abstract
The Thermodynamic Geometry (TG) of Mie fluids in the subcritical and supercritical region is studied using a third order thermodynamic perturbation theory equation of state (EOS). The R-crossing method of TG is applied to reproduce the coexistence curves related to Mie fluids and it is found that the validity of this methodology is range dependent. Besides, defining the R-Widom line, as the curve obtained from the extreme of the isotherms of the scalar curvature in the (P,T) plane, the behavior of this Widom line is analyzed varying the range and stiffness of Mie potentials and it is compared to the locus of the maxima of some response functions. A strong dependence of the R-Widom line is found with respect to stiffness and range potential for the Mie fluids. Besides, a kind of correspondence states principle it is found for the R-Widom line, and a Clausius–Clapeyron-type relation near the critical point in the supercritical region is fulfilled.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
