Studying the new modes of deposition of plasma coatings

Abstract

Problem. This paper considers using ion-plasma spraying of mold surfaces. This makes it possible to replace scarce and expensive tungsten-containing steels with other materials. Purpose. The purpose is to study the possibility of using the KIB method to increase the stability of die-casting molds, to establish the possibility of replacing scarce, expensive tungsten-containing steels with other materials. Materials and methods. 4Х5МФС and 5ХНМ steel grades were chosen as materials for copper alloy die-casting molds in this work. The choice of these steel grades is due to the fact that these steels do not contain tungsten due to its sharply increased scarcity and limited molybdenum content, and they also meet the requirements for the substrate material on which the titanium nitride coating is applied. Coatings were applied to samples for laboratory tests and die-casting mold parts by the condensation method with ion bombardment. Titanium nitride is applied at different partial nitrogen pressures – from 3×10-3 to 1 Pa to determine the required nitrogen pressure, which ensures that the working surfaces of mold parts receive coatings with the best performance characteristics. The coatings obtained at different nitrogen pressures differ in the amount and size of the droplet phase. Results of experiments. The largest amount of the droplet phase containing α-Ti is observed in coatings obtained at nitrogen pressures of 3×10-3 Pa, 3×10-2 Pa. An increase in nitrogen pressure (4×10-1 Pa, 1 Pa) significantly reduces the level of microdistortions of the crystal lattice in the coating, and its plasticity increases. In this regard, the coating's brittleness is reduced at a sufficiently high hardness. Results. The titanium nitride coating obtained at a nitrogen pressure of 1 Pa is the most effective in protecting the working surfaces of mold parts from destruction. Laboratory tests have shown that the titanium nitride coating applied under optimal process parameters increases the corrosion resistance of mold parts to which it is applied by 3 times and the scale resistance by 2-4 times.