Study on voltage clamping and self-humidification effects of pem fuel cell system with dual recirculation based on orthogonal test method

Abstract

Durability and reliability are still major challenges of vehicular polymer electrolyte membrane fuel cell (PEMFC) systems. With exhaust gas recirculation on both the anode and cathode sides, two important functions can be achieved: the voltage clamping in low current density, and the self-humidification without any external humidifiers. The former restrains catalyst decay in small load working conditions, and the latter is beneficial for improving the cold-start ability. In this study, dynamic performances and stable characteristics of a fuel cell system with dual exhaust gas recirculation are firstly experimentally studied using an orthogonal test method. System parameters, including humidification temperature of cathode external humidifier, fresh air stoichiometric ratio (SR), current density, cathode and anode recirculation pump speeds, are regarded as key factors in the experiments based on the testing conditions of the test-bench. Two four-factor and three-level orthogonal tables are designed, and the effects of key factors on system performance indices (average cell voltage, relative humidity (RH) at cathode inlet, high frequency resistance (HFR), oxygen concentrations at cathode inlet and outlet, and the concentration difference between these two positions) are investigated. Results show that: (1) with the cathode recirculation, the cell voltage can be reduced in low current densities by coordinately adjusting the recycled gas flow and reducing fresh air SR; (2) with the dual recirculation, the fuel cell membrane can be well hydrated, and system performance only shows 3% reduction compared with a system with an external humidifier; (3) the difference between the oxygen molar concentration at the inlet and outlet of cathode gas channels becomes small using dual recirculation.