Study on tritium transport characteristics in fluoride-salt-cooled high-temperature advanced reactor

Abstract

Fluoride-salt-cooled high-temperature reactors (FHRs) are a promising reactor class that combines prominent attributes from the Gen-Ⅳ reactors, raising attractive interests of the international community. However, tritium control has been a major challenge in FHRs because of the neutron reactions of lithium. It's necessary to study the transport characteristics of tritium in the fluoride-salt-cooled high-temperature advanced reactor (FuSTAR) and to provide theoretical support for appropriate tritium control measures and safe operation of the FHRs. In this paper, the inclusive transport characteristics of production, graphite adsorption, diffusion, dissolution, and permeation on tritium in the primary loop are analyzed. The mathematical and physical model of the tritium transport phenomenon is established, and an analysis model of tritium transport characteristics is also developed. Then, the tritium transport characteristics in the FuSTAR primary loop are analyzed. The results show that the tritium in the FuSTAR primary loop mainly exists in the form of Diatomic Tritium (T2), and it's found that Tritium Fluoride (TF) and T2 are adsorbed by graphite after being generated in the core, and this process reaches saturation in about 150 Effective Full Power Days (EFPDs). It also indicates that almost 48% of tritium penetrates the secondary loop through the heat exchanger, and only about 3.8% of tritium is adsorbed on the core graphite. TF makes the corrosion of the heat exchanger and downcomer more serious. Finally, the safety of tritium transport in FuSTAR is conservatively estimated, with a tritium emission dose of 0.1674 mSv/a. This study can provide a theoretical reference for the structural design, tritium recycling, and radiation protection of FHRs.