Study on tribological properties of UHMWPE irradiated by electron beam with TMPTMA and TPGDA as crosslinking agents

Abstract

Trimethylolpropane trimethacrylate (TMPTMA) and tripropylene glycol diacrylate (TPGDA) used as crosslinking agents were blended with ultra-high molecular weight polyethylene (UHMWPE or UPE) in alcohol, respectively. Then UPE plates were made by compression molding and electron beam (EB) irradiation crosslinking methods. FTIR, Soxhlet extractor, DSC, Wear tester and SEM were used for the characterization of all specimens. FTIR analyses show that trans-vinylene (965cm−1) absorption increases in all specimens and the >C=C< stretching absorption decreases after irradiation. Soxhlet experiments reveal that gel fraction increases with the increasing dose. DSC results indicate that Xc of all the irradiated UPEs are higher than that of unirradiated UPEs because of the free radical and small molecular which can promote the crystallization. Wear rate of 100kGy 1%TMPTMA/UPE and 1%TPGDA/UPE are 1.89×10−7mm3/(Nm) and 4.28×10−7mm3/(Nm), about 44.2% and 100% of that of 100kGy UPE, respectively, illustrating that TMPTMA is beneficial to reduce the wear rate of UPE and TPGDA almost has no effect to reduce the wear rate of UPE before 100kGy. SEMs of irradiated specimens are more smooth than that of unirradiated specimens. These can give some advice to improve tribological properties of UPE used in the friction field.