Abstract
A facile approach for the total synthesis of prenylated flavonoids, (±)-abyssinone-VI-4-O-methyl ether (1), (±)-abyssinone-IV-4'-O-methyl ether (2), (±)-abyssinone-V-4'-O-methyl ether (3) and (±)-sigmoidin E (4), has been de- scribed. The key intermediate 4-hydroxy-3,5-di-(3-methylbut-2-enyl)benzaldehyde (6) was synthesized that features regiose- lective prenylation of 4-hydroxybenzaldehyde and crystallizing with petroleum ether from the reaction mixture by freeze-out effect. All structures of new compounds were confirmed by IR, 1 H NMR, MS and HRMS techniques.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
