Abstract

transparent chalcogenide glass ceramics (ChGCs) based on a binary germanium-sulfur (Ge–S, GS) chalcogenide system were synthesized by heat treatment method. Compared with the precursor glass, the GS ChGCs embedded with GeS2 nanocrystals have the same infrared transparency, but smaller optical bandgap energy and higher mechanical strength. Z-scan measurements show that third-order optical nonlinearity in the GS ChGCs was remarkably enhanced, and this material would be suitable for applications in optical limiting.

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