Abstract

Abstract. This paper studies on the thermal decomposition analysis kinetics of nanometer powders. The DTA-TG-DTG curves obtain by SDT 2960 Simultaneous DSC-TGA analysis apparatus. Under the condition of N2atmosphere operation and rise temperature velocity was 10°C·min-1. The mechanism function dα/dt=κ(1-α)nis used to calculate the kinetics factors. Reaction progressionnwas obtained by calculation of the kissinger peak shape factor method. The results showed that the apparent activation energy of nano-Ni(OH)2was 254.027 KJ·mol-1, the pre-exponential factor was 3.062×1036, the reaction progression was obtained as 1.560, the kinetic equation is dα/dt=3.062×1036exp(-30554.166/T)(1-α)1.560

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