Abstract
In this report, a simple WO 3 dry lithiation is proposed for fabrication of all-solid-state electrochromic devices and characterized completely by X-ray photoelectron spectroscopy and electrochemical method. Lithiation is carried out by electron-beam evaporation of metal lithium, and the lithiated films have different components and electrochromic properties with different lithiation degrees. It is found that if Li/W ratio is less than 0.25, tungsten bronze Li x W0 3 is formed and the lithiated by wet method. Finally, a lithium-based all-solid-state electrochromic device with proper lithiation degree is fabricated using this dry method.
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