Study on the relationship between extreme pressure properties and component contents of high pressured sulfurized isobutylene

Abstract

PurposeCompared with traditional industrial processing technologies of sulfurized isobutylene, the one-step synthesis method involving high pressure is more environment-friendly and leads to better product performance. However, products from various sources perform differently because of the difference in the contents of their components. Therefore, the purpose of this study was to investigate the relationships between sulfide components of high-pressure sulfurized isobutylene and load carrying capacities.Design/methodology/approachA typical high-pressure sulfurized isobutylene was chosen, and the structure and contents of its sulfide components were characterized using gas chromatography-mass spectrometry and gas chromatography (GC). Extreme-pressure properties of the sample at different concentrations were evaluated using a four-ball tribometer.FindingsA multiple regression equation model was established, and tert-butyl trisulfide made the greatest contribution to the extreme-pressure properties according to the equation coefficient, while tert-butyl tetrasulfide had no effect. The results can be attributed to the fact that the structure of a sulfurized additive having an impact is application-specific.Originality/valueA precise and fast way to predict weld load values of high-pressure sulfurized isobutylene by using GC and the established equation model were successfully developed. Moreover, the empirical equation shows the relationships between sulfide component concentrations and load carrying capacities.