Abstract
Complextrans-[Mo(N2)2(dppe)2] (dppe=Ph2PCH2CH2PPh2) reacts with NN=CHCOOEt in benzene solution to afford benzene-azomethane,Ph-N=N-CH3, as the main organic product. However, the phosphazene speciesPh2P(N2CHCOOEt)(CH2CH2)P(N2CHCOOEt)Ph2 is formed by irradiating aTHF solution oftrans-[W(N2)2(dppe)2] in the presence of ethyldiazoacetate; in moist solution, the phosphazene bonds undergo a partial hydrolysis, and the phosphonium species [Ph2P(NHNCHCOOEt)(CH2CH2)P(NHNCHCOOEt)Ph2]2+ appears to be formed.
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