Abstract
The reactions of fluoroalkanesulfonyl azides 1 with some electron-rich compounds have been studied in detail. Cycloalkenyl vinyl ethers reacted with 1 readily at 0 °C to give the corresponding ring-contraction N-fluoroalkanesulfonyl amidine analogues 3 . In contrast, aryl ynamine generated in situ reacted with 1 affording fluorinated α-diazoamidines 9 , which were decomposed slowly at room temperature to form [1-diethylamino-2-(4-nitro-phenyl)-2-oxo-eth-( Z)-ylidene]-fluoroalkanesulfinyl imine 10 with elimination of nitrogen gas. Possible mechanisms for these reactions were proposed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
