Abstract

The ultra performance convergence chromatography method was developed to detect the migration of four phthalates (PAEs) in plastic food contact materials. Plastic food contact materials samples are immersed with oil-based (isooctane) and water-based simulants (10% ethanol, 4% acetic acid and water), respectively. The pre-treatment method of four kinds of PAEs in the simulated immersion solution was optimized. The relationship between migration behaviour and the simulants, migration temperature and migration time were studied. The results show that PAEs were more likely to migrate in oily simulants. Within a certain range, the migration amount increased with the extension of immersion time. The migration rate and amount enhanced with the temperature.

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